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KMID : 1059520070510020160
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Journal of the Korean Chemical Society
2007 Volume.51 No. 2 p.160 ~ p.164
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Synthesis of Aminofuroxan Derivatives for the Alkyne Formation on Solid Surface and e-Beam Mediated Fragmentation in Gas Phase
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Heo Jeong-Mu
Kim Gi-Young
Hwang Kwang-Jin
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Abstract
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Aminofuroxan derivatives 3 and 4 were prepared by the reaction of chlorofuroxan 2 with butyl and benzyl amines, respectively. E-beam mediated fragmentation of aminofuroxans 3, 4 in mass spectrometer was analyzed in a view of the corresponding alkyne formation.
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KEYWORD
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Alkyne, Furoxan, e-beam, Fragmentation
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